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Abstract The extraordinary 2021 September–October outburst of Centaur 29P/Schwassmann–Wachmann 1 afforded an opportunity to test the composition of primitive Kuiper disk material at high sensitivity. We conducted nearly simultaneous multiwavelength spectroscopic observations of 29P/Schwassmann–Wachmann 1 using iSHELL at the NASA Infrared Telescope Facility (IRTF) and nFLASH at the Atacama Pathfinder EXperiment (APEX) on 2021 October 6, with follow-up APEX/nFLASH observations on 2021 October 7 and 2022 April 3. This coordinated campaign between near-infrared and radio wavelengths enabled us to sample molecular emission from a wealth of coma molecules and to perform measurements that cannot be accomplished at either wavelength alone. We securely detected CO emission on all dates with both facilities, including velocity-resolved spectra of the CO (J= 2–1) transition with APEX/nFLASH and multiple CO (v= 1–0) rovibrational transitions with IRTF/iSHELL. We report rotational temperatures, coma kinematics, and production rates for CO and stringent (3σ) upper limits on abundance ratios relative to CO for CH₄, C₂H₆, CH₃OH, H₂CO, CS, and OCS. Our upper limits for CS/CO and OCS/CO represent their first values in the literature for this Centaur. Upper limits for CH₄, C₂H₆, CH₃OH, and H₂CO are the most stringent reported to date, and are most similar to values found in ultra CO-rich Oort cloud comet C/2016 R2 (PanSTARRS), which may have implications for how ices are preserved in cometary nuclei. We demonstrate the superb synergy of coordinated radio and near-infrared measurements, and advocate for future small-body studies that jointly leverage the capabilities of each wavelength. 

Abstract High-resolution near-infrared ground-based spectroscopic observations of comet 67P/Churyumov–Gerasimenko near its maximum activity in 2021 were conducted from the W. M. Keck Observatory, using the facility spectrograph NIRSPEC. 67P is the best-studied comet to date because of the unprecedented detail and insights provided by the Rosetta mission during 2014–2016. Because 67P is the only comet where the detailed abundances of many coma volatiles were measured in situ, determining its composition from the ground provides a unique opportunity to interpret Rosetta results within the context of the large database of ground-based compositional measurements of comets. However, previous apparitions, including in 2015, have been unfavorable for in-depth ground-based studies of parent volatiles in 67P. The 2021 apparition of 67P was thus the first-ever opportunity for such observations. We report gas spatial distributions, rotational temperatures, production rates, and relative abundances (or stringent upper limits) among seven volatile species: C₂H₂, C₂H₆, HCN, NH₃, CH₃OH, H₂CO, and H₂O. The measured abundances of trace species relative to water reveal near average or below average values compared to previous comets studied at infrared wavelengths. Both gas rotational temperatures and the spatial distributions of H₂O, C₂H₆, and HCN measured with Keck-NIRSPEC in 2021 are consistent with the outgassing patterns revealed by Rosetta in 2015 at very similar heliocentric distance  (post-perihelion). These results can be integrated with both Rosetta mission findings and ground-based cometary studies of the overall comet population, for which we encourage a wide-scale collaboration across measurement techniques. 

Abstract High-resolution infrared spectra of comet C/2014 Q2 Lovejoy were acquired with NIRSPEC at the W. M. Keck Observatory on two post-perihelion dates (UT 2015 February 2 and 3). H 2 O was measured simultaneously with CO, CH 3 OH, H 2 CO, CH 4 , C 2 H 6 , C 2 H 4 , C 2 H 2 , HCN, and NH 3 on both dates, and rotational temperatures, production rates, relative abundances, H 2 O ortho-to-para ratios, and spatial distributions in the coma were determined. The first detection of C 2 H 4 in a comet from ground-based observations is reported. Abundances relative to H 2 O for all species were found to be in the typical range compared with values for other comets in the overall population to date. There is evidence of variability in rotational temperatures and production rates on timescales that are small compared with the rotational period of the comet. Spatial distributions of volatiles in the coma suggest complex outgassing behavior. CH 3 OH, HCN, C 2 H 6 , and CH 4 spatial distributions in the coma are consistent with direct release from associated ices in the nucleus and are peaked in a more sunward direction compared with co-measured dust. H 2 O spatial profiles are clearly distinct from these other four species, likely due to a sizable coma contribution from icy grain sublimation. Spatial distributions for C 2 H 2 , H 2 CO, and NH 3 suggest substantial contributions from extended coma sources, providing further evidence for distinct origins and associations for these species in comets. CO shows a different spatial distribution compared with other volatiles, consistent with jet activity from discrete nucleus ice sources.